Noninnocent Dithiolene Ligands: A New Oxomolybdenum Complex Possessing a Donor−Acceptor Dithiolene Ligand

Noninnocent dithiolene ligands: a new oxomolybdenum complex possessing a donor-acceptor dithiolene ligand.

A new monoanionic dithiolene ligand is found in Tp*MoO(S(2)BMOQO). A combination of X-ray crystallography, electronic absorption spectroscopy, resonance Raman spectroscopy, and bonding calculations reveal that the monoanionic dithiolene ligand possesses considerable thiolate-thione character resulting from an admixture of an intraligand charge transfer excited state into the ground state wave f...

Dithiolene complexes as metallo-ligands: a crown-ether approach

Redox bifunctionality in a Pt(ii) dithiolene complex of a tetrathiafulvalene diphosphine ligand.

The Pt(ii) dithiolene complex of a tetrathiafulvalene diphosphine ligand exhibits two reversible redox systems at close potentials, localized on the weakly interacting TTF (tetrathiafulvalene) and Pt(dmit) moieties.

Infrared Multiple Photon Dissociation Spectroscopy of a Gas-Phase Oxo-Molybdenum Complex with 1,2-Dithiolene Ligands

Electrospray ionization (ESI) in the negative ion mode was used to create anionic, gas-phase oxo-molybdenum complexes with dithiolene ligands. By varying ESI and ion transfer conditions, both doubly and singly charged forms of the complex, with identical formulas, could be observed. Collision-induced dissociation (CID) of the dianion generated exclusively the monoanion, while fragmentation of t...

Complex Tuned by Metal Dithiolene Counteranions

Accepted Manuscripts are published online shortly after acceptance, which is prior to technical editing, formatting and proof reading. This free service from RSC Publishing allows authors to make their results available to the community, in citable form, before publication of the edited article. This Accepted Manuscript will be replaced by the edited and formatted Advance Article as soon as thi...